| SpectraBase Spectrum ID |
GrxeSvv5yWV |
| Name |
(1S,2S)-3-methyl-2-phenyl-3-(2-trimethylsilylethynyl)cyclobutanecarbaldehyde |
| Appearance |
Colorless oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Formula |
C17H22OSi |
| InChI |
InChI=1S/C17H22OSi/c1-17(10-11-19(2,3)4)12-15(13-18)16(17)14-8-6-5-7-9-14/h5-9,13,15-16H,12H2,1-4H3/t15-,16-,17?/m1/s1 |
| InChIKey |
GOVCEDZKNNIOCW-YNPPLXCJSA-N |
| Instrument Name |
Thermo Scientific DFS-HRMS |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.202001634 |
| Molecular Weight |
270.447 g/mol |
| Optical Rotation |
[a]D25 = +62 [c = 1, CH2Cl2) |
| Reported Formula |
C17H22OSi |
| SMILES |
[C@]1(CC([C@@]1(c1ccccc1)[H])(C#C[Si](C)(C)C)C)(C=O)[H] |
| SPLASH |
splash10-00di-0900000000-fb57b0cc46bc35da11ca |
| Sample Comments |
dr = 76:24, er = 87:13 (major), er = 94:6 (minor) |
| Source of Spectrum |
ACI-59-SM99-3ad |
| Thin-Layer Chromatography |
Rf = 0.33 (P/EtOAc, 9:1) |
| Wiley ID |
1857962 |
![rac-(1S,2S)-3-Methyl-2-phenyl-3-[(3-trimethylsilyl)ethynyl]cyclobutane-1-carbaldehyde](/api/spectrum/GrxeSvv5yWV/structure.png?h=300&w=458 "rac-(1S,2S)-3-Methyl-2-phenyl-3-[(3-trimethylsilyl)ethynyl]cyclobutane-1-carbaldehyde")
