| SpectraBase Spectrum ID |
DtPzUJLfxwW |
| Name |
(2R,4R)-1-(2-Bromo-4,5-dimethoxyphenyl)-2-methyl-4-((triisopropylsilyl)oxy)pentan-1-one |
| Appearance |
Colorless oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
486.180099267 u |
| Formula |
C23H39BrO4Si |
| InChI |
InChI=1S/C23H39BrO4Si/c1-14(2)29(15(3)4,16(5)6)28-18(8)11-17(7)23(25)19-12-21(26-9)22(27-10)13-20(19)24/h12-18H,11H2,1-10H3/t17-,18-/m1/s1 |
| InChIKey |
BXGCKONGJPDKEA-QZTJIDSGSA-N |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.202116625 |
| Molecular Weight |
487.550 g/mol |
| Optical Rotation |
[a]D20 = 0.9 (c = 1.00, CHCl3) |
| Quality |
81 |
| Reported Formula |
C23H39BrO4Si |
| SMILES |
C[C@](C[C@@](C)(C(C1=CC(=C(C=C1Br)OC)OC)=O)[H])(O[Si](C(C)C)(C(C)C)C(C)C)[H] |
| SPLASH |
splash10-00xr-2980000000-91b17026c769f07b3e4b |
| Sample Comments |
dr = 99:1, 98% ee |
| Source of Spectrum |
ACI-61-SM36-11a (DOI: 10.1002/anie.202116625) |
| Wiley ID |
1897507 |
