| SpectraBase Spectrum ID |
5giRdhh2O4y |
| Name |
4-((Tert-butyldimethylsilyl)oxy)-1-(6-methoxy-2,5,7,8-tetramethyl-chroman-2-yl)butan-2-one |
| Carrier Gas |
Hydrogen (30 ml/min, 1.2 bar) |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Formula |
C24H40O4Si |
| GC Column |
Optima-1-MS (30 m x 0.25 mm) |
| GC Oven Program |
Oven temp 300oC |
| InChI |
InChI=1S/C24H40O4Si/c1-16-17(2)22-20(18(3)21(16)26-8)11-13-24(7,28-22)15-19(25)12-14-27-29(9,10)23(4,5)6/h11-15H2,1-10H3 |
| InChIKey |
XZPYLNRZVPNUFX-UHFFFAOYSA-N |
| Instrument Name |
Agilent HP6890-5937 N |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/chem.202004843 |
| Molecular Weight |
420.665 g/mol |
| Optical Rotation |
[a]D20 = 9.74 (589nm) (c = 0.38/100ml, CH3Cl) |
| Quality |
211 |
| SMILES |
COC1=C(C2=C(C(=C1C)C)OC(CC2)(CC(CCO[Si](C(C)(C)C)(C)C)=O)C)C |
| SPLASH |
splash10-014i-1290100000-3c82ff29c078565a7e86 |
| Sample Comments |
92% ee |
| Source of Spectrum |
QE-27-SM47-12e (DOI: 10.1002/chem.202004843) |
| Thin-Layer Chromatography |
0.40 (SiO2, cHex/EtOAc, 5:1) |
| Wiley ID |
1901995 |
