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(+)-TRIETHYL-[(Z)-(1S,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE

Compound with spectra: 1 NMR

(+)-TRIETHYL-[(Z)-(1S,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE
SpectraBase Compound ID HEaPC3gG1cz
InChI InChI=1S/C30H45NO2SSi/c1-6-35(7-2,8-3)33-30(27-20-14-10-15-21-27)29(26-18-12-9-13-19-26)25(4)24-34(32,31-5)28-22-16-11-17-23-28/h9,11-13,16-19,22-24,27,29-30H,6-8,10,14-15,20-21H2,1-5H3/b25-24-/t29-,30-,34?/m0/s1
InChIKey XDZPMFWSVBRYCM-NLGFELCWSA-N
Mol Weight 511.8 g/mol
Molecular Formula C30H45NO2SSi
Exact Mass 511.294027 g/mol
Enantiomer InChIKey XDZPMFWSVBRYCM-NNLVUNNUSA-N

View Spectrum of (+)-TRIETHYL-[(Z)-(1S,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(+)-TRIETHYL-[(Z)-(1R,2R)-1,2-DIPHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-BUT-3-ENYLOXY]-SILANE
(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE
(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE
1-Butanone, 2-bromo-3-[(4-methylphenyl)sulfonyl]-1,3-diphenyl-
Cyclohexaneacetonitrile, 2-methyl-.alpha.-(methylphenylamino)-6-[(4-methylphenyl)sulfonyl]-
(1E,5E)-1,3-Diphenyl-6-(N-t-Butyldiphenylsilyl-S-phenylsulfonimidoyl)-1,5-hexadien-3-ol
2,3,8-TRIMETHYL-SPIRO-(CYCLOPENTANE-3,4-DIHYDRO-QUINAZOLINE)
(E)-(1SR,5SR,7RS,8SR)-3-(4'-Methoxycarbonylbutylidene)-7-tert-Butyldimethylsilyloxy-8-cyanobicyclo[3.3.0]octan-2-one
(E)-(1SR,5SR,7RS,8SR)-3-(4ï-METHOXYCARBONYLBUTYLIDENE)-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCTAN-2-ONE
(5E,1R*,2S*,4R*,8S*)1-[(tert-Butyldimethylsilyl)oxy]-5-(cyclohexylmethylene)-2-[(phenylsilyl)methyl]bicyclo[3.3.0]octane
Title Journal or Book Year
Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes Journal of the American Chemical Society 2004
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